منابع مشابه
Organocatalytic asymmetric epoxidation and tandem epoxidation/Passerini reaction under eco-friendly reaction conditions.
An eco-friendly synthesis of highly functionalized epoxides and their incorporation into an organocatalytic multicomponent approach are reported. For this, a modified class of diarylprolinol silyl ethers was designed to enable high catalytic activity in an environmentally benign solvent system. The one-pot procedure showed great efficiency in promoting stereoselective multicomponent transformat...
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The chemo-enzymatic epoxidation of rapeseed methyl ester (RME) in a solvent-free medium was studied using the immobilized Candida antarctica lipase B (Novozym® 435) as catalyst. Hydrogen peroxide (H2O2) was used as the oxygen donor. The enzyme cost is an important factor determining the economics of the process. High enzyme stability and the possibility to recycle the enzyme are therefore highl...
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Gold-titania based catalysts for the direct epoxidation of propene provide a clean and simple route for future propene oxide producing processes. These catalysts, producing propene oxide in a single step, have a moderate activity and a very high selectivity towards propene oxide. However, the hydrogen, which is used as a co-reactant, is used less efficient. To be able to improve the hydrogen ef...
متن کاملAn unexpected epoxidation of benzil derivatives in their reaction with a germene.
The germene Mes(2)Ge=CR(2) (Mes = 2,4,6-trimethylphenyl, CR(2) = fluorenylidene) reacts with various benzil derivatives to lead to germanium-containing bicyclic epoxides by an unexpected new type of epoxidation reaction.
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1958
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.16.712